The cubes people photograph and disbelieve come almost entirely from one mine at Navajún in La Rioja, Spain, where pyrite grew in a soft marl that let the crystals develop unimpeded faces. The result is cubes so geometrically clean that the usual first reaction is that they must be man-made.
They are not, and there is a way to tell. Natural Navajún cubes carry very fine parallel striations on their faces, and the striations run at right angles between adjacent faces — a growth feature of the cubic system that no polishing produces. They also sit in or on a pale grey-brown matrix, often with the impression of the crystal still in the rock, and the faces have minute growth steps rather than a uniform polish.
Cultured pyrite exists and is sold legitimately. It tends to come as loose cubes with no matrix, in matched sizes, with faces that are flat and bright but striation-free. Neither is a fake; the difference is what you are paying for.
References and sizesNavajún, La Rioja (Spain) · Pyritohedron · Interpenetrant twins
Establish which of these you are holding before judging it. A genuine piece read against another reference's rules will look wrong when it is not.